不:先行词被不确定的数量词修饰(any, every, each, few, little, no, some, all 等),或者先行词是不定代词(all, something, nothing, anything等)
I am sorry fro all the things that I did to you.
I want to buy something that will make me look younger.
避:当句中已经有 who 或 which 时,为避免重复,只能用 that
Who is the man that is giving us the class?
Which is the book that you want to buy?